The synthesis and thermal behavior of di[m-hydroxo-diaquo (squarato) of métals trivalents (Fe, Al and Ga)

  • Louiza ZENKHRI Univ Ouargla, Fac. des Mathématiques et des Sciences de la Matière, Ouargla 30 000 (Algérie)
  • Ahmed BOUTARFAIA Univ Ouargla, Fac. des Mathématiques et des Sciences de la Matière, Ouargla 30 000 (Algérie)
  • Thierry BATAILLE Laboratoire Sciences Chimiques de Rennes (CNRS, UMR 6226), Universite´ de Rennes 1, France
  • Nathalie AUDEBRAND Laboratoire Sciences Chimiques de Rennes (CNRS, UMR 6226), Universite´ de Rennes 1, France
Keywords: ORGANIC-INORGANIC HYBRID MATERIALS, THERMODIFFRACTOMETRY

Abstract

A new series of mixed metals and squarates of formula [M(C4O4)(OH)(H2O)2]22H2O with (M=Al,Ga) has been synthesized, wen we report a work on the preparation of mixtures, the goal was to prepare a porous hybrid phase. But we obtained the phase prepared previously by J. T. Wobleski and D. B. Brown, thus of new phase belonging to the same family (Di[m-hydroxo-diaquo squarato of de trivalents metals). So we have also obtain this phase as well as with metal gallium (Ga) and aluminum (Al). The thermal decomposition of the precursors has been studied in vacuum between 100 and 600 °C, by powder thermodiffractometry for a compound of this family (M = Al) followed by a comparison between the temperature connect to thermal degradation of three compounds of this family. It is shown that crystalline intermediate phases are formed during the degradation.

Published
2014-10-15
How to Cite
ZENKHRI, L., BOUTARFAIA, A., BATAILLE, T., & AUDEBRAND, N. (2014). The synthesis and thermal behavior of di[m-hydroxo-diaquo (squarato) of métals trivalents (Fe, Al and Ga). Annals of Science and Technology, 6(2), 5. Retrieved from https://journals.univ-ouargla.dz/index.php/AST/article/view/396
Issue
Vol 6 No 2 (2014): volume 6 numéro 2 2014
Section
Articles